Thermo-chemical behaviour of Dunaliella salina biomass and valorising their biochar for naphthalene removal from aqueous rural environment.

Thermo-chemical behavior of a microalgal biomass; Dunaliella salina was investigated through thermo-gravimetric analyses. Fully-grown D. salina biomass were subjected for biochar conversion using pyrolytic treatment at three distinct heating rates such as 2.5, 5, and 15 °C min-1. The kinetic appraisals were explained by using model-free kinetics viz., Kissinger-Akahira-Sanose, Flynn-Waal-Ozawa and Starink iso-conversional correlations with concomitant evaluation of activation energies (Ea). The Ea value is 194.2 kJ mol-1 at 90% conversion in FWO model, which is higher as compared to other two models. Moisture, volatile substances, and other biochemical components of the biomass were volatilized between 400 and 1000 K in two separate thermo-chemical breakdown regimes. Microscopic and surface characterization analyses were carried out to elucidate the elemental and morphological characteristics of the biomass and biochar. Further, the proficiency of the prepared biochar was tested for removing naphthalene from the watery media. The novelty of the present study lies in extending the applicability of biochar prepared from D. salina for the removal of a model polyaromatic hydrocarbon, naphthalene.

Conversion of solid wastes and natural biomass for deciphering the valorization of biochar in pollution abatement: A review on the thermo-chemical processes.

This overview addresses the formation of solid trash and the various forms of waste from a variety of industries, which environmentalists have embraced. The paper investigates the negative effects on the environment caused by unsustainable management of municipal solid trash as well as the opportunities presented by the formal system. This examination looks at the origins of solid waste as well as the typical treatment methods. Pyrolysis methods, feedstock pyrolysis, and lignocellulosic biomass pyrolysis were highlighted. Explain in detail the various thermochemical processes that take place during the pyrolysis of biomass. Due to its carbon content, low cost, accessibility, ubiquitousness, renewable nature, and environmental friendliness, biomass waste is a unique biochar precursor. This study looks at the different types of biomass waste that are available for treating wastewater. This study discussed a wide variety of reactors. Adsorption is the standard method that is used the most frequently to remove hazardous organic, dye, and inorganic pollutants from wastewater. These pollutants cause damage to the environment and water supplies, thus it is important to remove them. Adsorption is both simple and inexpensive to utilize. Temperature-dependent conversions explain the kinetic theories of biomaterial biochemical degradation. This article presents a review that explains how pyrolytic breakdown char materials can be used to reduce pollution and improve environmental management.

Conductive polymer layered semiconductor for degradation of triclopyr acid and 2,4-dichlorophenoxyacetic acid from aqueous stream using coalesce adsorption-photocatalysis technique.

Polyaniline supported titanium dioxide nanoparticles (PTs) were fabricated using chemical oxidative aniline polymerization in the presence of titanium dioxide with ammonium peroxydisulfate as an oxidant. The synthesized PTs were thoroughly characterized for their morphological and functional features. PTs were employed for the photodegradation of acidic herbicides; 2,4-dichlorophenoxyacetic acid (2,4-D) and triclopyr acid (TCP). PT's surface modifications were imparted and their herbicide removal efficiencies were compared. The best operating conditions for adsorption/photocatalysis were 0.5 g/L photocatalyst, 10 mg/L concentration of individual herbicides resulted in 90.72% removal of TCP at pH 4 and 99.91% removal of 2,4-D at pH 5. Adsorption kinetics of herbicides, onto PT-1 showed the equilibrium attainment within 30 min and experimental data obeyed pseudo-second order model for TCP and 2,4-D removal which was governed by chemisorption. Analysis of TCP and 2,4-D adsorption indicated that the removal followed Sips model for TCP removal while Redlich-Peterson model explained the removal of 2,4-D by PT-1. Rate constants indicated that the amount of TiO2 in the PTs played an important role in removing the herbicides and PT-1 material excellent remarkable activity for three cycles of photodegradation. Thus, this work reports the polymerization of aniline onto TiO2 and their utility as photocatalyst for the expulsion of 2,4-D and TCP from water.

Titanium dioxide based nanocomposites - Current trends and emerging strategies for the photocatalytic degradation of ruinous environmental pollutants.

Many ruinous pollutants are omnipresent in the environment and among them; pesticides are xenobiotic and pose to be a bio-recalcitrance. Their detrimental ecological and environmental impacts attract attention of environmental excerpts and the surge of stringent regulations have endows the need of a technically feasible treatment. This critical review emphasizes about the occurrence, abundance and fate of structurally distinct pesticides in different environment. The practiced remedial strategies and in particular, the advanced oxidation processes (AOPs) those utilize the photo-catalytic properties of nano-composites for the degradation of pollutants are critically discussed. Photo-catalytic degradation utilizes many composite materials at nano-scale level, wherein synthesis of nano-composites with appropriate precursors and other adjoining functional moieties are of prime importance. Therefore, suitable starter materials along with the reaction conditions are prerequisite for effectively tailoring the nano-composites. The aforementioned aspects and their customized applications are critically discussed. The associated challenges, opportunities and process economics of degradation using photo-catalytic AOP techniques are highlighted and in addition, the review tries to explain how best the photo-degradation can be a stand-alone tool with a societal importance. Conclusively, the future prospects for undertaking new researches in photo-catalytic breakdown of pollutants that can be judiciously sustainable.

Nanocellulose/TiO2 composites: preparation, characterization and application in the photocatalytic degradation of a potential endocrine disruptor, mefenamic acid, in aqueous media.

Nanocellulose (NC)-supported TiO2 nanoparticles, termed NCTs, were prepared by an ultrasonic impregnation method. The as-synthesized NCTs were thoroughly characterized and studied for the photodegradation of mefenamic acid (MEF), an anthranilic acid derivative drug. The adsorption potential of NCTs increased with TiO2 loading and 10 wt% TiO2 NCT showed the highest sorption potential. Adsorption kinetics of MEF onto NC and NCTs indicated that the equilibrium was reached within 50 min. A pseudo-second-order model clearly represented the experimental kinetic data and demonstrated that the MEF sorption was mainly chemisorption. Equilibrium sorption analysis indicated that the adsorption followed the Langmuir model with a monolayer sorption capacity of 22.43 mg g-1 for 10 wt% TiO2 NCT. The photocatalytic degradation rates of NCTs were identical with respect to their adsorption capacities, and the apparent rate constant (kapp) values indicated that the amount of TiO2 in NCTs played a vital role in the degradation of MEF. Furthermore, 10 wt% TiO2 NCT showed excellent catalytic activity and reusability even after five cycles of photodegradation.